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The chemistry of the tripeptide, the gamma-bond, the thiol on the central cysteine, the recycling cycle of GSH and GSSG — all of these appear remarkably consistent across organisms separated by enormous evolutionary distances

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The toxicity may be enhanced, perhaps synergistically, by oxidative stress and by Michael adduction between aminoacrylate and susceptible nucleophiles such as GS − and protein sulfhydryls and/or by modification of coenzyme in susceptible PLP enzymes